Consider this picture (taken from Hatcher pg 106). Elements of $\Delta_n(X)$, called $n$-chains, can be written as finite formal sums $\sum_\alpha n_\alpha e^n_\alpha$ with coefficients $n_\alpha\in\mathbb{Z}$, and $e^n_\alpha$ are open $n$-simplices.
I can guess that $2e$ means the edge going around anticlockwise twice (is that correct?)
However, I don't know what $2v$ would represent? Or for that matter $-v$?
Thanks for enlightening!