If $H \cong \mathbb{K}[G]$ for some group $G$, then one can just take the elements of $G$ as the distinct group-like elements.
For the other implication recall than in any coalgebra the set of group-like elements is linearly independent, and that in any Hopf algebra the set of group-like elements forms a group with respect to the multiplication of $H$.
If an $n$-dimensional Hopf algebra $H$ contains $n$ distinct group-like elements, then it follows that $G$, the set of group-like elements in $G$, is linearly independent and contains at least $n$ elements.
Thus $G$ is a a basis of $H$.
Thus we may identify $H$ with $\mathbb{K}[G]$ as $\mathbb{K}$-vector spaces.
The multiplication of $G$ is the restriction of the multiplication of $H$, and so the multiplication of $H$ turns out to be the unique $\mathbb{K}$-bilinear extension of the multiplication of $G$.
This shows that the multiplication of $H$ coincides with the one of $\mathbb{K}[G]$.
(It also follows their units coincide.)
The comultiplication and counit of $H$ are given on the basis $G$ by $\Delta(g) = g \otimes g$ and $\varepsilon(g) = 1$ (because the elements $g \in G$ are group-like).
This hows that the comultiplication and counit of $H$ also coincide with the one of $\mathbb{K}[G]$.
Alltogether we have found that $H \cong \mathbb{K}[G]$.