For a given function $\alpha: [0, 1]\to \mathbb{R}$, let's denote $\mathcal{R}(\alpha)$ to be the set of all Riemann-Stieltjes integral functions with respect to $\alpha$. It is a well-known fact that (for example, see Theorem 6.8 in Rudin's Principles of Mathematical Analysis) if $f: [0,1]\to\mathbb{R}$ is a continuous function, and $\alpha: [0,1]\to\mathbb{R}$ is a monotonically increasing, then $f\in\mathcal{R}(\alpha)$.
I am interested in the following:
Question 1: What is an example of function $\alpha:[0,1]\to\mathbb{R}$ and a continuous function $f:[0,1]\to\mathbb{R}$ such that $f\not\in\mathcal{R}(\alpha)$?
Question 2: Does there exist an example of continuous function $\alpha:[0,1]\to\mathbb{R}$ and a continuous function $f:[0,1]\to\mathbb{R}$ such that $f\not\in\mathcal{R}(\alpha)$?
Thanks!