A $(R,S)$-bimodule $M$ is the same as either a ring map $S^{op}\to \mathrm{hom}_R(M,M)$ or a ring map $R\to \mathrm{hom}_{S^{op}}(M,M)$ (i.e. $M$ can be viewed as $(S^{op},R^{op})$-bimodule). Since any ring $R$ is an $(R,R)$-bimodule, there are ring maps $R^{op}\to \mathrm{hom}_R(R,R)$ and $R\to \mathrm{hom}_{R^{op}}(R,R)$; it turns out that these maps are isomorphisms, hence $\mathrm{hom}_R(R,R)^{op}=\mathrm{hom}_{R^{op}}(R,R)$.
Now, given a $(R,R)$-bimodule $M$, is it true that the maps $R^{op}\to \mathrm{hom}_R(M,M)$ and $R\to \mathrm{hom}_{R^{op}}(M,M)$ are dually equivalent, and in particular $\mathrm{hom}_R(M,M)^{op}=\mathrm{hom}_{R^{op}}(M,M)$? Thanks for your help