The angles are $\angle C = \arctan(\sqrt{3}/2) \approx 40.9^\circ$, $\angle A = 120^\circ$, and $\angle B = 60^\circ- \angle C = \arcsin\left(\frac{\sqrt{3}}{2\sqrt{7}}\right)\approx 19.1 ^\circ$.
Longer Answer:
We can use coordinate geometry. WLOG by shifting, rotating, and scaling, let $C = (0,0)$ and $A = (1,0)$ with $B = (x,y)$ unknown.
Then $G = \left(\frac{x+1}{3},\frac{y}{3}\right)$.
We have our two conditions as follows:
First, by the definition of the tangent function,
$$\angle GCA = 30^\circ \implies \frac{y/3}{(x+1)/3} = \tan(30^\circ) = \frac{1}{\sqrt{3}}$$
so we have
$$y = \frac{x+1}{\sqrt{3}}$$
Second, note that continuing the line $AG$ intersects the midpoint $D$ of $BC$, which is at coordinates $(x/2,y/2)$.
We use the dot-product formula
$$\sqrt{3}/2 = \cos(30^\circ) = \frac{AD \cdot AB}{||AD|| \hspace{5pt}||AB||}$$
where the vectors are
$$AD = (x/2 - 1, y/2)$$
$$AB = (x-1,y)$$
Squaring,
$$
\frac{3}{4} = \frac{\left((x/2 - 1)(x-1)+(y/2)y\right)^2}{((x/2-1)^2+(y/2)^2)((x-1)^2+y^2)}$$
Substituting in our above formula for $y$ and simplify through a lot of algebra,
$$\frac{3}{4} = \frac{16x^4-56x^3+105x^2-98x+49}{16x^4-56x^3+108x^2-92x+52}$$
Multiplying out the denominator, we get a degree-4 polynomial whose solutions are $x = 1/2$, $x=2$ and two complex solutions.
$x=1/2$ is the equilateral triangle, and $x=2$ corresponds to the other solution you found with $y = \sqrt{3}$.
Then the angles are $\angle C = \arctan(\sqrt{3}/2) \approx 40.9^\circ$, $\angle A = 120^\circ$, and $\angle B = 60^\circ- \angle C \approx 19.1 ^\circ$.